The green paradox: The metallurgical challenge of the energy transition
Keywords:
Bioethanol, corrosion, green inhibitors.Abstract
The energy transition towards the use of bioethanol in automobiles poses a “green paradox”: its high hygroscopicity facilitates water ingress and the formation of acetic acid, causing severe localized corrosion in engine metals. To overcome this challenge, materials science is developing molecular-level barriers. This article outlines the mechanisms behind this damage and explores three cutting-edge strategies: the use of protective amines in bio-blends, the design of “tailor-made” petrochemical additives, and the development of botanical “green inhibitors,” ensuring durable and truly sustainable engines.
References
Szabó, Á. I., Mursi, Z. T., Wégerer, A. y Nagy, G. (2025). Comprehensive efficiency analysis of ethanol–gasoline blends in spark ignition engines. Eng, 6(10), 256. https://doi.org/10.3390/eng6100256
Baroš, P., Matějovský, L., Macák, J., Staš, M. y Pospíšil, M. (2022). Corrosion aggressiveness of ethanol–gasoline and butanol–gasoline blends on steel: Application of electrochemical impedance spectroscopy. Energy & Fuels, 36(5), 2616-2629. https://doi.org/10.1021/acs.energyfuels.1c03680
Arik, E., Altan, H. y Esenturk, O. (2014). Dielectric properties of ethanol and gasoline mixtures by terahertz spectroscopy and an effective method for determination of ethanol content of gasoline. The Journal of Physical Chemistry A, 118(17), 3081-3089. https://doi.org/10.1021/jp500760t
Brito-Franco, A., Uruchurtu, J., Rosales-Cadena, I., López-Sesenes, R., Serna-Barquera, S. A., Hernández-Pérez, J. A., Rocabruno-Valdés, C. y González-Rodríguez, J. G. (2020). Corrosion behavior of Al in ethanol–gasoline blends. Energies, 13(21), 5544. https://doi.org/10.3390/en13215544
Matějovský, L., Staš, M., Li, K., Baroš, P., Kudrnová, M. y Macák, J. (2025). Mild steel corrosion in gasoline blends with acetone–butanol–ethanol and inhibition efficiencies of amines. Energy & Fuels, 39(20), 9487-9506. https://doi.org/10.1021/acs.energyfuels.5c01404
Matějovský, L., Macák, J., Pleyer, O., Straka, P. y Staš, M. (2019). Efficiency of steel corrosion inhibitors in an environment of ethanol–gasoline blends. ACS Omega, 4(5), 8650-8660. https://doi.org/10.1021/acsomega.8b03686
Nogueiron-Benitez, D. A., Gálvez-Larios, A. K., López-Sesenes, R., Ramírez-Arteaga, A. M. y González-Rodríguez, J. G. (2025). A study of the corrosion inhibition of aluminum in ethanol-gasoline blend using Annona muricata leaves extract. Journal of Bio- and Tribo-Corrosion,11(1), Artículo 3. https://doi.org/10.1007/s40735-024-00923-4
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